This is an exciting issue of Action Comics #333 from DC Comics, published in February 1966.
The comic features the iconic superheroes Superman (Clark Kent), Superboy Kal-El, Cal Ellis, Ardora (Lex's Wife, Cameo), Jimmy Olsen, Perry White, Tom Vance, Superwoman (Carole Zorelle, Also Disguised As Tir-An), Superwoman Robot X-21, Lex Luthor, and Jimmy Olsen (Also Disguised As Van-Dal).
The cover art is done by Curt Swan and Sheldon Moldoff, and this Silver Age (1956-69) era comic book is a must-have for any Superman fan or collector of comics.