This place is likely the Old Tucson Studios in Tucson, Arizona, which served as a primary filming location for the 1966 Western film El Dorado starring John Wayne.     

The distinctive adobe-style building and the mountain visible in the background are known landmarks of the studio's set, often referred to as Golden Gate Mountain or Cat's Back Mountain.  

The photo appears to be an on-location shot during the filming of the movie. 

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